Toss together peppers and garlic in oil; spread on large baking sheets. Roast at 350 degrees for 15 minutes. Add all ingredients to a large stockpot. Bring to a boil over medium-high heat; reduce heat and simmer for 15 minutes. Spoon into jars, leaving 1/4-inch headspace. Wipe rims; secure with lids and rings. Process in a boiling water bath for 15 minutes. Set jars on towels to cool; check for seals.
Tip: Keep an eye out for vintage silver spoons at flea markets…oh-so clever tied onto giftable jars of salsa, jam, jelly or relish.
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